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Question

For the reaction
2A+B3C at 298K, Kc=49
A 3L vessel contains 2,1 and 3 moles of A,B and C respectively. The reaction at the same temperature:

A
must proceed in forward direction
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B
must proceed in backward direction
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C
must be in equilibrium
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D
cannot be predicted
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Solution

The correct option is A must proceed in forward direction
For the reaction
2A+B3C at 298K, Kc=49
A 3L vessel contains 2,1 and 3 moles of A,B and C respectively. The reaction at the same temperature must proceed in forward direction.
Qc=[C]3[A]2[B]
Qc=( 3 mol 3 L )3( 2 mol 3 L )2×( 1 mol 3 L )
Qc=6.75
But Kc=49
Qc<Kc
The product concentration is less than equilibrium value.
The reactant concentration is more than the equilibrium value.

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