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Question

For the reaction 2Fe(NO3)3+3Na2CO3Fe2(CO3)3+6NaNO3, initially 2.5 mol of Fe(NO3)3 and 3.6 mol of Na2CO3 is taken. If 6.3 mol of NaNO3 is obtained then, % yield of given reaction is:

A
50%
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B
84%
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C
87.5%
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D
100%
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Solution

The correct option is C 87.5%
2Fe(NO3)32.5 mole+3Na2CO33.6 moleFe2(CO3)3+6NaNO36.3 mole
To find limiting reagent
for Fe(NO3)3=2.52=1.25
for Na2CO3=3.63=1.2
Here the limiting reagent is Na2CO3, so NaNO3 formed (theoretically) will be 3.6 mol of Na2CO3×6 mol of NaNO33 mol of Na2CO3=7.2 mol of NaNO3
Percentage yield=Actual yieldtheoretical yield×100=6.37.2×100=87.5%

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