For the reaction 2N2O5(g)→4NO2(g)+O2(g) −Δ[N2O5]Δt=k1[N2O5],+[NO2]Δt=k2[N2O5],+Δ[O2]Δt=k3[N2O5] Thus,
A
2k1=4k2=k3
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B
2k1=k2=4k3
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C
k1=k2=k3
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D
None of these
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Solution
The correct option is B2k1=k2=4k3 For the reaction 2N2O5(g)→4NO2(g)+O2(g)
Rate of the reaction: −12d[N2O5]dt=k12N2O5](i) 14d[NO2]dt=k24[N2O5](ii) d[O2]dt=k3[N2O5](iii)
all are rate of reaction thus i=ii=iii 2k1=k2=4k3