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Question

For the reaction
2N2O5(g)4NO2(g)+O2(g)
Δ[N2O5]Δt=k1[N2O5],+[NO2]Δt=k2[N2O5],+Δ[O2]Δt=k3[N2O5] Thus,

A
2k1=4k2=k3
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B
2k1=k2=4k3
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C
k1=k2=k3
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D
None of these
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Solution

The correct option is B 2k1=k2=4k3
For the reaction
2N2O5(g)4NO2(g)+O2(g)
Rate of the reaction:
12d[N2O5]dt=k12N2O5] (i)
14d[NO2]dt=k24[N2O5] (ii)
d[O2]dt=k3[N2O5] (iii)
all are rate of reaction thus
i=ii=iii
2k1=k2=4k3

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