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Question

For the reaction 3BrOBrO3+2Br in an alkaline aquesous solution, the value of the second order (inBrO) rate at 80 in the rate law for Δ[BrO]Δt was found to be 0.056 mol L1s1. What is the rate when the rate law is written for (a) ΔBrO3Δt,(b)ΔBrΔt

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Solution

3BrOBrP3+2Br
13Δ[BrO]Δt=Δ[BrO3]Δt=12Δ[Br]Δt
Δ[BrO]Δt=3Δ[BrO3]dt
Δ[BrO3]Δt=13×0.056=0.0181
Δ[Br]Δt=23Δ[BrO]Δt
=23×0.056=0.0382

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