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Question

For the reaction A(g)+3B(g)2C(g)+D(g,) initial mole of A is twice that of B, if at equilibrium, mole of B is half of moles of C then percent of B reacted is

A
75
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B
45
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C
91
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D
32
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Solution

The correct option is A 75
A+3B2C+D
Initial concentration a a/2 0 0
At equilibrium (a-x) (a/2-3x) 2x x
We have been given that at equilibrium moles of B is half of mole of C
i.e. a23x=12(2x)
x=a8
Therefore, the maount of B reacted =3x=3a8
Initial amount of B =a2
So, % of B reacted =Amount of B reactedInitial amount of B×100
% of B reacted =3a8a2×100=75%

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