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Byju's Answer
Standard XII
Chemistry
Order of Reaction
For the react...
Question
For the reaction
A
→
products, the following data is given for a particular
run time
time (imn)
0
5
15
35
1
[
A
]
(
M
−
1
)
1
2
4
8
Determine the order of the reaction.
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Solution
For time t=0, conc [A]=1
For time t=5, conc [A]=0.5
For time t=15, conc [A]=0.25
For time t=35, conc [A]=0.125
It is seen that the concentration is decreasing at an increasingly faster rate and that this decrease is not linear.
Therefore it can be concluded that the given reaction is of order 2.
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Similar questions
Q.
For the reaction
A
→
products, the following data is given for a particular run.
time(min): 0 5 15 35
1
[
A
]
(
M
−
1
)
: 1 2 4 8
Determine the order of the reaction.
Q.
For a first order reaction
A
→
products, the rate of reaction at
[
A
]
=
0.2
M
is
1
×
10
−
2
m
o
l
l
i
t
−
1
m
i
n
−
1
. The half life period for the reaction is:
Q.
The following data are for the reaction
A
+
B
→
p
r
o
d
u
c
t
s
:
Conc. A Conc. B Initial Rate
(M) (M) (
m
o
l
L
−
1
s
−
1
)
0.1 0.1
4.0
×
10
−
4
0.2 0.2
1.6
×
10
−
3
0.5 0.1
2.0
×
10
−
3
0.5 0.5
1.0
×
10
−
2
(i) What is the order with respect to A and B for the reaction?
(ii) Calculate the rate constant.
(iii) Determine the reaction rate when the concentrations of A and B are 0.2 M and 0.35 M, respectively.
Q.
Sr.No.
[
A
]
0
/
M
(lonic conc.)
[
B
]
0
/
M
(lonic conc.)
rate/
(
M
s
e
c
−
1
)
1
1.6
×
10
−
3
5
×
10
−
2
10
−
3
2
3.2
×
10
−
3
5
×
10
−
2
4
×
10
−
3
3
1.6
×
10
−
3
10
−
1
2
×
10
−
3
4
3.2
×
10
−
3
10
−
1
8
×
10
−
3
For the reaction
A
+
B
⟶
C
; starting with different initial concentration of A and B, initial rate of reaction were determined graphically in four experiments :
Rate law for reaction from above data is :
Q.
The following are the data for the reaction
A
+
B
→
products
[A] [B] Initial rate
(
m
o
l
L
−
1
s
−
1
)
(i) 0.1 M 0.1 M
4.0
×
10
−
4
(ii) 0.2 M 0.2 M
1.6
×
10
−
3
(iii) 0.5 M 0.1 M
1.0
×
10
−
2
(iv) 0.5 M 0.5 M
1.0
×
10
−
2
What is the order of the reaction?
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