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Question

For the reaction, H2(g)+CO2(g)CO(g)+H2O(g), if the initial concentration of [H2]=[CO2]=1 and x mol/litre of H2 is consumed at equilibrium, the correct expression of Kp is:

A
x2(1x)2
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B
(1+x)2(1x)2
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C
x2(2+x)2
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D
x21x2
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Solution

The correct option is A x2(1x)2

Explanation:

H2(g)+CO2CO+H2O(g)

Initial concentration: 1 1 0 0

At equilibrium: (1x) (1x) x x


KP=PCO×PH2OPH2PCO2=x×x(1x)×(1x)=x2(1x)2


Hence the correct answer is option A.


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