For the reaction H2(g)+I2(g)⇋2HI(g) Kc=66.9 at 350∘C and Kc=50.0 at 448∘C the reaction has
A
△H=+ve
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B
△H=−ve
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C
△H=zero
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D
△H sign can not be determined
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Solution
The correct option is B△H=−ve H2(g)+I2(g)⇋2HI(g)logK2K1=△H2.303R[1T1−1T2] Given K1=66.9 T1=350∘Cor623KK2=50T2=448∘Cor721Klog5066.9=△H2.303R[1623−1721] After calculation negative value of △H is obtained.