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Question

For the reaction
H2(g)+I2(g)2HI(g)
Kc=66.9 at 350C and Kc=50.0 at 448C the reaction has

A
H=+ve
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B
H=ve
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C
H=zero
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D
H sign can not be determined
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Solution

The correct option is B H=ve
H2(g)+I2(g)2HI(g)logK2K1=H2.303R[1T11T2]
Given K1=66.9
T1=350Cor623KK2=50T2=448Cor721Klog5066.9=H2.303R[16231721]
After calculation negative value of H is obtained.

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