For the reaction K4[Fe(CN)6]⟶Fe3++CO2+NO⊖3, the n-factor is:
A
1
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B
11
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C
53
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D
61
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Solution
The correct option is B 61 +1×4K4[Fe2+(−1×6CN)6]−4 Oxidation state of Fe is +2. Fe2+⟶Fe3++e− 6(CN)⊖⟶6CO2+12e− 6(x−3=−1)6(x−4=0) 6(x=2)6(x=4) 6(CN)⊖⟶6NO⊖3+48e−