For the reaction : MnO2+4HCl100%−−−→MnCl2+Cl2+2H2O, 17.4gMnO2 is dissolved in 500mL of HCl solution containing 7.3gHCl per litre. (molar mass of Mn=55g/mol)
A
HCl is the limiting reagent
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B
MnO2 is the limiting reagent
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C
0.05 moles of MnCl2 will form
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D
1120 mL Cl2 gas will be liberated at 0oC and 1 atm
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Solution
The correct option is D 1120 mL Cl2 gas will be liberated at 0oC and 1 atm MnO2+4HCl100%−−−→MnCl2+Cl2+2H2O
moles of MnO2=17.487=0.2
moles of HCl=7.336.5=0.2
moles of MnO2stoichiometric coefficeint=0.21=0.2
moles of HClstoichiometric coefficeint=0.24=0.05
HCl is a limiting reagent.
4 moles of HCl form 1 mole of Cl2 nCl2formed from 0.2 mol of HCl=0.05
as molar volume at STP = 22.4L VCl2=0.05×22.4=1120mL
Similarly, moles of MnCl2=14moles of HCl nMnCl2=0.05