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Question

For the reaction :N2O5(g)2NO2(g)+0.5O2(g)
The mole fraction of N2O5(g) decomposed at constant volume and temperature is 4×10x,then calculate the value of x. if the initial pressure is 600 mm Hg and the pressure at any time is 960 mm Hg is.
Assume ideal behaviour.

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Solution

N2O5(g)2NO2(g)12O2(g)InitialPPmmHg00FinalPaftertimetPp2p12p
Total pressure = Pp+2p+12p
=P+32p
Thus, P240 mm
Mole fraction of N2O5 decomposed = PP=240960=0.4

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