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Question

For the reaction, O(g)+O2(g)O3(g);ΔHo=107.2 kJ. Hence, the average bond energy in O3 is:

(Assume O=O bond energy 498.8 kJ mol1)

A
606.0 kJ mol1
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B
107.2 kJ mol1
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C
391.6 kJ mol1
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D
303.0 kJ mol1
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Solution

The correct option is D 303.0 kJ mol1
O2(g)+O2(g)O3 ΔH=107.2KJ/mol

To calculate average bond enthalpy in O3

The equation of the bond enthalpy is
the change in enthalpy of reaction = (the sum of the bonding energy of reactants)-(the sum of the bonding energy of the products)

The change of enthalpy is given as = 107.2KJ/mol

-107.2KJ/mol =(bond enthalpy sum of reactants)-2(bond enthalpy sum of products)

-107.2KJ/mol = 498.7KJ/mol-2(bond enthalpy of products)

498.7KJ/mol is the BE of O2

its 2 times the bonding enthalpy products because of their 2 kinds of bonds in O3- a single and a double bond

605.9KJ/mol = 2BE

BE of products = 303.0KJ/mol

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