The correct option is A △U<0,W=0
Bomb calorimeter is commonly used to find the heat of combustion of organic substances which consists of a sealed combustion chamber called a bomb, if a process is run in a sealed container then no expansion or compression is allowed, so, W = 0 and △U=q..since, reaction is exothermic , heat will released .Thus it has △U<0, W = 0.