For the reaction SOCl2+H2O⟶SO2+2HCl the enthalpy of reaction is 49.4kJ and the entropy of reaction is 336JK−1. Calculate ΔG at 300K and predict the nature of the reaction.
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Solution
ΔG=ΔH−TΔS =49.4−(300×336×10−3)=−51.4kJ Since, the free energy change is negative, the given reaction is spontaneous.