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Question


For the reduction of NO3 ion in an aqueous solution E is +0.96 V. Values of E for some metal ions are given below:
V2+(aq)+2eV;E0=1.19V
Fe3(aq)+3eFe;E=0.04V
Au3+(aq)+3eAu;E=+1.40V
Hg2+(aq)+2eHg;E0=+0.86V
The pair(s) of metals that is/are oxidised by NO3 in aqueous solution is (are)

A
V and Hg
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B
Hg and Fe
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C
Fe and Au
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D
Fe and V
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Solution

The correct options are
A V and Hg
B Hg and Fe
D Fe and V
Metals with E value less than 0.96 V will be able to reduce NO3 in aqueous solution. Therefore, metals V(E=1.19V),Fe(E=0.04V),Hg(E=0.86V) will all reduce NO3 but Au(E=1.40V) cannot reduce NO3 in aqueous solution.

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