For the two gaseous reactions, following data is given : A→B;k1=1010e−20000/T C→D;k2=1012e−24606/T the temperature at which k1 becomes equal to k2 is:
A
400K
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B
1000K
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C
800K
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D
1500K
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Solution
The correct option is B1000K A→B;k1=1010e−20000/TC→D;k2=1012e−24606/T when k1=k2 1010e−20000/T=1012e−24606/T e4606/T=100 4606T=2.303log100=2.303×2 ∴ T=46062.303×2=1000K