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Byju's Answer
Standard XII
Chemistry
Difference between Internal Energy and Enthalpy
For which of ...
Question
For which of the following cases,
Δ
S
=
Δ
H
T
?
A
Process of which
Δ
C
P
=
0
, but
Δ
C
V
=
0
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B
An isothermal process
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C
An isobaric process
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D
An isothermal reversible phase transition process
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Solution
The correct option is
D
An isothermal reversible phase transition process
As we know,
Δ
S
=
q
T
and for isothermal reversible phase transition process,
Δ
S
=
Δ
H
T
as
q
=
Δ
H
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Q.
Assertion :A process of expansion of an ideal gas which is isothermal as well as adiabatic must be free-expansion process. Reason: A reversible isothermal process can also be adiabatic only at
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Q.
Hello sir/ma'am
My doubt is that for an isothermal reversible process why should ∆H = 0? Shouldn't it have some other value because there is a change in volume?( ∆H=∆U+P∆V, ∆U=0 )
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