For which of the following $d^{n}$ configuration of octahedral complex(es), can not exist in both spin and low spin forms?

d^{3}

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d^{5}

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d^{6}

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d^{8}

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Solution

The correct options are
A $d^{3}$
D $d^{8}$
Both $d^{3} a n d d^{8}$ electronic configurations are independent of the ligand field strength.
Hence, they can not exist in both spin and low spin forms.

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d^{6}

C . F . S . E

[F e C l_{6}]^{3 -}

[F e (C N)_{6}]^{3 -}

[F e (C N)_{6}]^{3 -}

d^{5}

d^{5}

Δ_{0} =

P =

d^{6} -

(Δ_{0} =

)

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