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Question

For which of the following reaction H=E+2RT

A
N2(g)+3H2(g)2NH3(g)
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B
N2(g)+O2(g)2NO(g)
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C
NH4HS(s)NH3(g)+H2S(g)
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D
PCl5(g)PCl3(g)+Cl2(g)
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Solution

The correct option is D NH4HS(s)NH3(g)+H2S(g)
ΔH=ΔE+ΔngasRT
Comparing with ΔH=ΔE+2RT
Δngas=2
1Δngas=213=(2)
2Δngas=211=0
3Δngas=1+10=2
4Δngas=1+11=1

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