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Question

For which of the following types of dn configuration, the number of unpaired electrons in octahedral complexes remains same irrespective of the ligand field strength.

A
d3
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B
d4
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C
d5
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D
d6
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Solution

The correct option is A d3
For d3 configuration, the number of unpaired electrons in octahedral complexes remains same irrespective of the ligand field strength.
Three electrons are present in t2g level and are unpaired. When the fourth electron enters, the ligand field strength will determine whether it will pair up or not.

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