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Question

Formation of ClF3 from Cl2 and F2 is an exothermic process. The equilibrium system can be represented as:
Cl2(g)+3F22ClF3; ΔH=329kJ
Which of the following will increase quantity of ClF3 in the equilibrium mixture?

A
Increase in temperature, decrease in pressure, addition of Cl2
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B
Decrease in temperature and pressure, addition of ClF3
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C
Increase in temperature and pressure, removal of Cl2
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D
Decrease in temperature, increase in pressure, addition of F2
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Solution

The correct option is D Decrease in temperature, increase in pressure, addition of F2
Cl2+3F22ClF3;ΔH=329KJ
Since it is releasing energy, it is an exothermic reaction. Exothermic reactions favours making of bonds i.e formation of ClF3, and the reaction proceeds towards rightside at low temperatures, high pressures and also the addition of reactants F2

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