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Question

Formation of metallic copper from the sulphide ore in the commercial thermo-metallurgical process essentially involves which one of the following reactions?

A
Cu2S+32O2Cu2O+SO2 ; CuO+CCu+CO
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B
Cu2S+32O2Cu2O+SO2; 2Cu2O+Cu2S6Cu+SO2
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C
Cu2S+2O2CuSO4; CuSO4+Cu2S3Cu+2SO2
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D
Cu2S+32O2Cu2O+SO2; Cu2O+CO2Cu+CO2
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Solution

The correct option is B Cu2S+32O2Cu2O+SO2; 2Cu2O+Cu2S6Cu+SO2
In the extraction of copper, reactions occurs:
2Cu2S+3O22Cu2O+2SO2
Cu2S+2Cu2O6Cu+SO2
and
2Cu2S+5O22CuSO4+2CuO
2Cu2S+CuSO44Cu+2SO2
Also, copper is not reduced by carbon/carbon monoxide.
Option B is correct.

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