Formation of metallic copper from the sulphide ore in the commercial thermo-metallurgical process essentially involves which one of the following reactions?
A
Cu2S+32O2→Cu2O+SO2 ; CuO+C→Cu+CO
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B
Cu2S+32O2→Cu2O+SO2; 2Cu2O+Cu2S→6Cu+SO2
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C
Cu2S+2O2→CuSO4; CuSO4+Cu2S→3Cu+2SO2
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D
Cu2S+32O2→Cu2O+SO2; Cu2O+CO→2Cu+CO2
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Solution
The correct option is BCu2S+32O2→Cu2O+SO2; 2Cu2O+Cu2S→6Cu+SO2 In the extraction of copper, reactions occurs: 2Cu2S+3O2→2Cu2O+2SO2 Cu2S+2Cu2O→6Cu+SO2 and 2Cu2S+5O2→2CuSO4+2CuO 2Cu2S+CuSO4→4Cu+2SO2 Also, copper is not reduced by carbon/carbon monoxide. Option B is correct.