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Question

Formation of Ni(CO)4 and its subsequent decomposition into Ni and CO (recycled) makes basis of Mond's process.

Ni+4COT1−→Ni(CO)4T2−→Ni+4CO
T1 and T2 are:

A
100oC, 50oC
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B
50oC, 100oC
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C
50oC, 230oC
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D
230oC, 50oC
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Solution

The correct option is D 50oC, 230oC
In the Mond's process, nickel is extracted and purified. Impure nickel reacts with carbon monoxide at 5060oC temperature and forms Ni(CO)4 leaving all the impurities, then Ni(CO)4 is heated to 220250oC to give pure nickel and carbon monoxide.

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