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Question

Formic acid is considered as a resonance hybrid of the four structures Which of the above order is correct for the stability of the four contributing structures :

HO||COHHO|C=+OHHO|+COHHO+|COH
I II III IV

A
I>II>III>IV
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B
I>II>IV>III
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C
I>III>II>IV
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D
I>IV>III>II
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Solution

The correct option is A I>II>III>IV
The compound without charge is most stable. The greater the number of covalent bonds, the greater the stability since more atoms will have complete octets. Therefore HCOOH is most stable.
The octet is complete and the number of pie bond is more in II.
A structure with a negative charge on the more electronegative atom will be more stable +CHOOH.
A structure with a positive charge on the more electronegative atom with incomplete octet will not be stable +OHCOH is least stable. the order is I>II>III>IV

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