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Question

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them:

A
O2<NO<C22<He+2
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B
C22<He+2<O2<NO
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C
He+2<O2<NO<C22
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D
NO<O2<C22<He+2
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Solution

The correct option is C He+2<O2<NO<C22
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing them,
First we will calculate the bond order for all elements.
Bond order=NbNa2
Nb=Number of electrons in bonding molecular orbital
Na=Number of electrons in anti0bonding molecular orbital
NO=15 electrons
σ1s2,σ1s2,σ2s2,σ2s2,σ2p2z,π2p2x=π2p2y,π2p1x
B.O=832=2.5
O2=17 electrons
σ1s2,σ1s2,σ2s2,σ2s2,σ2p2z,π2p2x=π2p2y,,π2p2x=π2p1y
B.O=852=1.5
C22=14 electrons
σ1s2,σ1s2,σ2s2,σ2s2,σ2p2z,π2p2x=π2p2y
B.O=822=3
He2+2=3 electrons
σ1s2,σ1s1
B.O=212=0.5
Therefore order is He+2<O2<NO<C22

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