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Question

Four different experiments were conducted in the following ways-

I) 3g of carbon was burnt in 8g of oxygen to give 11g of CO2.

II) 1.2g of carbon was burnt in air to give 4.2g of CO2.

III) 4.5g of carbon was burnt in enough air to give 11g of CO2.

IV) 4g of carbon was burnt in oxygen to form 30.3g of CO2.

Law of constant proportions is illustrated in which of the following experiment(s)?

A
I and III only
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B
II and III only
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C
IV only
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D
I only
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Solution

The correct option is D I only
The law of definite proportion or law of constant composition states that a given chemical compound always contains its component elements in a fixed ratio (by mass) and does not depend on its source and method of preparation.

In the option, A, 3g of carbon reacts with 8g of oxygen to form 11g of carbon dioxide.

C+O2CO2(g)
3+8=11

Thus, it follows the law of constant proportion. Option D is correct.

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