Four sets of carbanions (a-d) with the factors responsible for their stability to a certain extent are given. Identity the carbanion with wrong explanation of stability.

$C L_{3} ⊖ C : : p π - d π$ bond

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$: C H_{3} - C \equiv ⊖ . . C$ :sp Hybrid Orbitals

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$H_{2} ⊖ C - N O_{2}$ : Nucleophilic nature of $N O_{2}$ group

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Solution

The correct option is D
$H_{2} ⊖ C - N O_{2}$ : Nucleophilic nature of $N O_{2}$ group

$N O_{2}$ group is electron with drawing group and not nucleophilic.

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(C H_{3})_{3} C^{-}, C l_{3} C^{-}, (C H_{3})_{2} H C^{-}, C_{6} H_{5} H_{2} C^{-}

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