The correct option is A Liquid-liquid
Fractional distillation is a separation process for liquid-liquid mixture into its component parts, or fractions.
The separation depends on the difference in the boiling point (usually 25 oC at 1 atm) of individual components. The mixture is heated to a temperature at which one or more fractions of the compound will vaporize.
For boiling point difference greater than 25 oC, a simple distillation is used.