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Question

Freshly prepared sucrose solution, in the presence of an acid catalyst, on warming, exhibits a change in optical activity. This is known as:

A
misquotation.
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B
inversion.
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C
commiseration.
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D
Amdori rearrangement.
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Solution

The correct option is B inversion.
Sucrose and glucose are dextrorotatory, while fructose is laevorotatory. Hence, during hydrolysis, the angle of rotation decreases from +ve value to ve value, in aggregate. This is called as inversion of cane sugar.
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