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Question

From the following compounds which does not react with C6H5SO2Cl?

A
C2H5NH2
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B
CH3NH2
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C
(CH3)2NH
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D
(C2H5)3N
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Solution

The correct option is D (C2H5)3N
Tertiary amines, due to lack of H-atom, attached directly with N, does not react with benzene sulphonyl chloride (C6H5SO2Cl) i.e, Hinsberg's reagent.

(C2H5)3N is a tertiary amine, so does not react with C6H5SO2Cl.

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