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Byju's Answer
Standard XII
Chemistry
Rate Constant
From the foll...
Question
From the following data find the order of decomposition of
H
2
O
2
in aqueous solution.
Time (in minutes) 0 10 20
Volume(in c.c. of
K
M
n
O
4
) 22.8 13.3 8.25
If X is order, then X is ____.
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Solution
From the given, data, it can be concluded that the reaction is of the first order.
For first order reaction,
k
=
2.303
t
l
o
g
a
a
−
x
For
t
=
10
,
k
=
2.303
10
l
o
g
22.8
13.3
=
0.05
For
t
=
20
,
k
=
2.303
20
l
o
g
22.8
8.23
=
0.05
Thus,
X
=
1
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Q.
Volume of
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(in cc)
Time (in minutes)
6.25
10
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15
11.4
20
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35.05
∞
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Q.
From the following data estimate the order for decomposition of an aqueous solution of hydrogen peroxide:
Time (minutes)
0
10
20
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V
(
m
l
)
46.1
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12.3
where
V
is the volume of potassium permanganate solution in
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L
required to decompose a definite volume of the peroxide solution.
Q.
The decomposition of hydrogen peroxide in an aqueous solution is a reaction of first order. It can be followed by titrating 10 mL portions of reaction mixture at various times from the beginning of reaction against a standard solution of
K
M
n
O
4
. Volume of
K
M
n
O
4
solution used in each case is proportional to the remaining concentration of
H
2
O
2
. From the following data, calculate the rate constant of the reaction.
Time (in seconds)
0
600
1200
K
M
n
O
4
sol. used (in mL)
22.8
13.8
8.20
Q.
Decomposition of
H
2
O
2
follows a first order reaction. In fify minutes the concentration of
H
2
O
2
decreases from
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to
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M
in one such decomposition. When the concentration of
H
2
O
2
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will be:
Q.
The decomposition of hydrogen peroxide in an aqueous solution is a reaction of first order. It can be followed by titrating 10 mL portions of reaction mixture at various times from the beginning of reaction against a standard solution of
K
M
n
O
4
. Volume of
K
M
n
O
4
solution used in each case is proportional to the remaining concentration of
H
2
O
2
. From the following data, calculate the rate constant of the reaction.
Time (in seconds)
0
600
1200
K
M
n
O
4
sol. used (in mL)
22.8
13.8
8.20
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