The correct option is D Fe2+,Mn2+
Isoelectronic refers to two atoms, ions, or molecules that have the same number of total electrons and the same number of valence electrons.
(a) O2− and F− both have 10 electrons
(b) Na+ and Mg2+ both have 10 electrons
(c) Mn2+ and Fe3+ both have 23 electrons
(d) Fe2+ has 24 electrons.
Mn2+ has 23 electrons.
So, option (d) is correct.