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Question

From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.

(i) 3 NO(g) → N2O (g) Rate = k[NO]2

(ii) H2O2 (aq) + 3 I(aq) + 2 H+ → 2 H2O (l) + Rate = k[H2O2][I]

(iii) CH3CHO(g) → CH4(g) + CO(g) Rate = k [CH3CHO]3/2

(iv) C2H5Cl(g) → C2H4(g) + HCl(g) Rate = k [C2H5Cl]

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Solution

(i) Given rate = k [NO]2

Therefore, order of the reaction = 2

Dimension of

(ii) Given rate = k [H2O2] [I]

Therefore, order of the reaction = 2

Dimension of

(iii) Given rate = k [CH3CHO]3/2

Therefore, order of reaction =

Dimension of

(iv) Given rate = k [C2H5Cl]

Therefore, order of the reaction = 1

Dimension of


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