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Question

From which of the following reaction is blister copper obtained?

A
Cu2S+FeO2Cu+FeO
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B
Cu2S+FeS2Cu+FeS2
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C
Cu2S+2Cu2O6Cu+SO2
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D
Cu2++FeFe2++Cu
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Solution

The correct option is B Cu2S+2Cu2O6Cu+SO2
The formed molten copper when cooled gives off dissolved SO2. The SO2 gas escaping in the form of bubbles leaves the surface of the metal full of cavities, which gives the metal a blistered appearance. This is why the metal obtained is blister copper.
Reaction:
Cu2S+2Cu2O6Cu+SO2

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