Gaseous reaction A → B + C follows first order kinetics. Concentration of A changes from 1 M to 0.25 M in 138.6 minutes. Find the rate of reaction when concentration of A is 0.1 M.
A
2×10−3M/min
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B
10−3M/min
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C
10−4M/min
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D
5×10−4M/min
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Solution
The correct option is B10−3M/min 2t1/2=138.6t1/2=138.62K=0.693t1/2R=K.[A]=0.69369.3×0.1=10−3M/min