The correct option is
D no free surface
Correct option (d): no free surface.
Free surface of gases
- Gases do not have definite shape and volume.
- There is almost no force of attraction between the molecules of a gas.
- The dispersed nature of gas molecules does not allow the gases to have a free surface.
- The molecules of gases possess translatory motion and move in a random direction.
- Therefore, they do not have a fixed position and no free surface can be observed.
- In terms of a solid, liquid, or gas, the free surface is the surface where surface tension occurs.
Explanation for incorrect options
Option (a)
- Solids do have a fixed shape and fixed volume.
- The intermolecular force of attraction between the molecules of solids is high.
- As the molecules of solid are fixed at their positions due to the high intermolecular force of attraction.
- They do not possess translatory motion.
- Due to the fixed position of molecules, solids have many free surfaces.
- In terms of a solid, liquid, or gas, the free surface is the surface where surface tension occurs.
- The surface that is free or in contact with air has a balance of force to maintain it.
- For example, brick is made up of mud and this mud is made up of small particles like dry dirt and some amount of water.
- When masonry makes brick, by which we can initiate the building design.
- This small brick will convert into a big building with an infinite number of surfaces.
Option (b)
- Liquids have fixed volume but they do not have a fixed shape.
- Intermolecular force of attraction between liquid molecules is less as compared to solids but the molecules are bound by a force of attraction.
- Due to the presence of this intermolecular force, liquid has only one free surface at its top layer.
Thus, gases have no free surface.
Hence, option (d) is correct.