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Question

Generally, the first ionization enthalpy increases along a period with few exceptions. Choose the correct option which is not an exception.

A
N and O
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B
Na and Mg
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C
Mg and Al
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D
Be and B
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Solution

The correct option is B Na and Mg
In spite of higher nuclear charge, the ionization enthalpy of O < N , Al < Mg and B < Be. The reason for all these is the half-filled electronic configuration.

However, in case of Na and Mg, ionization enthalpy increases as the nuclear charge increases and therefore, is not an exception.

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