The process in which, a large number of monomer units connect together to form a large macromolecule (polymer) of different sizes and lengths is called polymerization reaction.
It is a process by which monomer units are converted into polymers.
Polymerization reactions are mostly chain reactions.
Examples are polyethene from ethylene, polystyrene from styrene, polyvinyl chloride (PVC) from vinyl chloride, polypropylene from propylene, etc.
Hence, an example of a polymerization reaction is, ethylene polymerizes to form polyethene as follows,