Physisorption | Chemisorption |
It involves physical or van der Waals forces between the particles of adsorbate and adsorbent. | It involves chemical bonds (covalent bonds) between adsorbate and adsorbent particles. |
It has low heat of adsorption (20 to 40 kJ/mol) | It has high heat of adsorption (40 to 200 kJ/mol) |
It is relatively weak. | It is relatively strong. |
Adsorption is multilayer. | Adsorption is monolayer. |