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Question

Give any one reaction of Swartz, Wurtz and Finkelstein reaction of alkyl halides.

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Solution

Swarts reaction : It is one of the best rxn. to produce fluoroalkane. When alkyl chloride / alkyl bromide is heated in presence of metallic fluoride ( such as AgF,Hg2F2,CoF2 etc ), alkyl fluoride is produced
ex. CH3CH2Cl+AgFCH3CH2F+AgCl
The Wurtz reaction, is a coupling reaction whereby two alkyl halides are reacted with sodium metal in dry ether solution to form a higher alkane
CH3CH2Cl+Na(dry ether)CH3CH2CH2CH3+NaCl
Finkelstein reaction is the treatment of a primary alkyl halide with an alkali metal iodide (e.g. KI) that leads to replacement of the halogen via an SN2 Reaction with I
CH3CH2Cl+KICH3CH2I+KCl

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