Give balanced equations for the following named reactions: (i) Reimer-Tiemann reaction (ii) Rosenmund reaction (iii) Hoffmann's degradation reaction
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Solution
(ii) C2H5COClPropionylchloride+H2Pd/BaSO4−−−−−−−−−−→inboilingxyleneC2H5CHOPropionaldehyde+HCl (iii) C2H5CONH2Propanamide+Br2+4KOH⟶C2H5NH2Ethylamine+2KBr+2H2O+K2CO3