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Question

Give one chemical test to distinguish between Aniline and benzylamine.

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Solution

Can be distinguished by their reaction with the help of HNO2. Benzylamine resees with HNO2 to form unstable diazonium salt, with the evolution of
N2 gas. C6H5CH2NH2+HNO2C6H5CH2+HCL+N2
C6H5NH2+HNO2C6H5N+2CL+Nacl+H2O

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