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Question

Give reasons why:
Zinc displaces lead from lead nitrate solution while gold is unable to do so.


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Solution

Zn displaces Pb fromPbNO32 but Au cannot:

  • The activity series of metals helps in determining the reactivity of the metals. The metal having more reactivity can replace the metal having less reactivity.
  • The reactivity of the metal is in the order:
  • K>Na>Ca>Mg>Al>Zn>Fe>Sn>
  • Pb>[H]>Cu>Hg>Ag>Au>Pt
  • The reactivity of zinc is very higher than lead so Zinc can replace lead.
  • Whereas the reactivity of gold is very low than lead, so gold cannot replace lead.

Zn+PbNO32ZnNO32+PbAu+PbNO32Noreaction


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