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Question

Give scientific reasons.
When a brass article is silver plated, it is used as cathode.

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Solution

In silver plating, the object to be plated i.e. brass article is made from cathode of an electrolytic cell. The anode is a bar of silver metal, and the electrolyte is a solution of silver cyanide; AgCN in water.

When a direct current is passed through the cell, Ag+ from AgCN migrates to the cathode (brass material), where they are neutralized by electrons and stick to the brass materials as silver metals.


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