Give the correct order of initials True (T) or False (F) for the following statementsI) sp^3 hybrid orbitals are at 90^∘ to one anotherII)Adjacenet sp^3d^2 hybrid orbitals are at 90 to one anotherIII) sp^3 hybrid orbitals are at 120 to one anotherIV) Bond order of N O bond in NO

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Idea of Hybridisation

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TFTF

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TTFF

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FTTT

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FTFT

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Solution

The correct option is D FTFT
(1) $s p^{3}$ orbitals have $109^{0} 28^{1}$ angle b/w them.
(3) $s p^{3}$ orbitals don't have $120^{0}$ angle.
(4) B.O. $\frac{> 1}{2}$ (Bonding $e^{-}$ -Antibonding $e^{-}$ ) for N-O bond $(15 e^{-})$
but here bond order can be calculated using charge
$4 e^{-} p a i r s / 3 b o n d s = 1 \cdot 33 e^{-}$ per bond.
So B.O. $= 1 \cdot 33 = \frac{4}{3} = 1 \frac{1}{3}$
So any is FTFT

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