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Question

Give the equation when ethanoic acid reacts with phosphorus pentachloride.


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Solution

Equation when ethanoic acid reacts with phosphorus pentachloride

  • Acetyl chloride (CH3COCl) is formed when ethanoic acid (CH3COOH) is heated with phosphorus pentachloride (PCl5).
  • The -COOH group is changed to the -COCl group in this reaction.
  • Phosphorus oxychloride (POCl3) and Hydrochloric acid (HCl) are the byproducts.
  • The chemical equation can be given as follows.

PCl5(s)phosphoruspentachloride+CH3COOH(aq)ethanoicacidCH3COCl(l)acetylchloride+HCl(aq)hydochloricacid+POCl3(l)phosphorusoxychloride


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