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Introduction to Geometric Isomerism

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Question

Give the IUPAC name of $[T i (H_{2} O)_{6}]^{3 +}$ . Draw cis and trans isomers of $[P t (N H_{3})_{2} C l_{2}]$ .

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Solution

The IUPAC name of $[T i (H_{2} O)_{6}]^{3 +}$ is $h e x a a q u o t i t a n i u m (I I I) .$

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Q. a) Draw cis and trans isomers of

C H C l = C H C l .

Also, write their IUPAC names.
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Q. Draw cis and trans isomers of

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Q. Draw cis and trans isomers of the following compounds. also write their

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C H C I = C H C I

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Q. The anti-cancer drug cis-platin has the formula

P t (N H_{3})_{2} C l_{2}

. There is another isomer, trans-platin, that is not medically active. What is the shape of cis-platin?

Dipole moment will be zero in the complexes

I) $[N i (C N)_{4}]^{2 -}$

II) $C i s - [P t (N H_{3})_{2} C l_{2}]$

III) Trans - $[P t (N H_{3})_{2} C l_{2}]$

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