Give the structures of $A, B$ and $C$ in the following reactions:
$C H_{3} C H_{2} I N a C N \to A O H - - ---------- \to P a r t i a l h y d r o l y s i s B N a O H + B r_{2} \to C$

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Solution

The structures of $A, B$ and $C$ in the following reactions are as shown:
(i) $C H_{3} C H_{2} I N a C N - --- \to C H_{3} C H_{2} C N (A) O H^{-} - ---------- \to P a r t i a l h y d r o l y s i s C H_{3} C O N H_{2} (B) N a O H + B r_{2} - ------ \to C H_{3} N H_{2} (C)$

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Give the structures of A,B and C in the following reactions :

(i) CH3CH2INaCN−−−−→AOH−−−−−−−−−−−−→Partial hydrolysisBNaOH+Br2−−−−−−−→C

(ii) C6H5N2ClCuCN−−−−→AH2O−−→BNH3−−−→ΔC

(iii) CH3CH2BrKCN−−−→ALiAIH4−−−−−→BHNO2−−−−→0∘C

(iv) C6H5NO2Fe/HCI−−−−−→ANaNO2+HCl−−−−−−−−→273KBH2O/H+−−−−−→ΔC

(v) CH3COOHNH3−−−→ΔANaOBr−−−−→BNaNO2/HCl−−−−−−−−→C

(vi) C6H5NO2Fe/HCl−−−−−→AHNO2−−−−→273BC6H5OH−−−−−→C

C H_{3} C H_{2} O H K_{2} C r_{2} O_{7} / H_{2} S O_{4} - --------- \to o x i d a t i o n A C a C O_{3} - --- \to B d r y d i s t i l - ---- \to C

C H_{3} {C H}_{2} O H o x i d a t i o n - ---------- \to K_{2} {C r}_{2} O_{7} / H_{2} {S O}_{4} A_{3} B d r y d i s t i l ⟶ C

A, B

C

C H_{3} B r K C N - ------ \to A L i A l H_{4} - ------- \to B H N O_{2} - ------- \to 273 K C

C H_{3} C O O H N H_{3} - ------ \to Δ A {B r}_{2} + K O H - --------- \to B C H {C l}_{3} + N a O H - ------------ \to C

Give the structures of A, B and C in the following reactions:

(i)

(ii)

(iii)

(iv)

(v)

(vi)

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