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Oxidation of Alcohols

Give the stru...

Question

Give the structures of products $A, B a n d C$ in the following reactions:
(i) $C H_{3} C H_{2} B r K C N ⟶ A L i A l H_{4} ⟶ B H N O_{2} - --- \to 0^{o} C C$
(ii) $C H_{3} C O O H N H_{3} - -- \to Δ A N a O H + B r_{2} ⟶ B C H C L_{3} + A l c . K O H ⟶ C$

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Solution

$(i) C H_{3} C H_{2} B r K C N - -- \to C H_{3} C H_{2} C N L i A l H_{4} - --- \to C H_{3} C H_{2} C H_{2} N H_{2} H N O_{2} - --- \to C H_{3} C H_{2} C H_{2} O H$

$(i i) C H_{3} C O O H N H_{3} - -- \to C_{6} H_{5} C O N H_{2} N a O H + B r_{2} - ------ \to C H_{3} N H_{2} C H C l_{3} + A l c . K O H - ---------- \to C H_{3} N^{+} \equiv C^{-}$

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Similar questions

C H_{3} C H_{2} B r K C N - -- \to A L i A l H_{4} - --- \to B H N O_{2} - --- \to 0^{\circ} C C

C H_{3} C O O H N H_{3} - -- \to Δ A N a O H + B r_{2} - ------ \to B C H C l_{3} + A l c . K O H - ---------- \to C

A, B

C

C H_{3} B r K C N - ------ \to A L i A l H_{4} - ------- \to B H N O_{2} - ------- \to 273 K C

C H_{3} C O O H N H_{3} - ------ \to Δ A {B r}_{2} + K O H - --------- \to B C H {C l}_{3} + N a O H - ------------ \to C

Give the structures of A, B and C in the following reactions:

(i)

(ii)

(iii)

(iv)

(v)

(vi)

A, B

C

C H_{3} C H_{2} I N a C N \to A O H - - ---------- \to P a r t i a l h y d r o l y s i s B N a O H + B r_{2} \to C

A

A N H_{3} \to 1 m o l B C H C l_{3} \to A l c . K O H C R e d u c t i o n \to (C H_{3})_{2} C H N H C H_{3}

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