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Question

Give two chemical tests to distinguish propan-2-ol and 2-methylpropan-2-ol.

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Solution

(i) When propan-2-ol and 2-methyl-propan-2-ol are treated with copper at 573k, different products are formed. From the nature of the products we can distinguish them.
(ii) Lucas test. When propan-2-ol and 2-methyl-propan-2-ol are treated with lucas reagent(conc. HCl+ anhydrous ZnCl2) at room temperature, from the turbidity formation, we can distinguish them.
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